Direct synthesis of hierarchical zeolite from a natural layered material.
نویسندگان
چکیده
Hierarchical SAPO-34 zeolite with high crystallinity and excellent hydrothermal stability was directly synthesized in the nanoscale confined environment provided by the natural layered material kaolin.
منابع مشابه
Effects of the Framework and Mesoporosity on the Catalytic Activity of Hierarchical Zeolite Catalysts in Benzyl Alcohol Conversion
Zeolites are crystalline inorganic porous materials formed by TO4 tetrahedra (T=Si, Al, P, etc.) with ordered microporous structures. As a result of their tunable acidities and framework structures, zeolites have been used widely in catalysis and molecular adsorption/separation as well as several other emerging applications. However, the pore size of a zeolite is usually smaller than 2 nm, whic...
متن کاملPreparing hierarchical nanoporous ZSM-5 zeolite via post-synthetic modification of zeolite synthesized from bagasse and its application for removal of Pb2+
In this study, hierarchical H-ZSM-5 zeolite is prepared via post-synthetic modification of parent H-ZSM-5 zeolite (Si/Al=35) synthesized from bagasse (BGA) as silica source using desilication with alkaline treatment (AT). For optimizing the effective parameters on desilication, Taguchi method was utilized. Cultivated BGA in the south of the Caspian Sea (Mazandaran province, Iran) is applied for...
متن کاملSingle-step delamination of a MWW borosilicate layered zeolite precursor under mild conditions without surfactant and sonication.
Layered borosilicate zeolite precursor ERB-1P (Si/B = 11) is delaminated via isomorphous substitution of Al for B using a simple aqueous Al(NO3)3 treatment. Characterization by PXRD shows loss of long-range order, and TEM demonstrates transformation of rectilinear layers in the precursor to single and curved layers in the delaminated material. N2 physisorption and base titration confirm the exp...
متن کاملSynthesis of nanocomposite based on Semnan natural zeolite for photocatalytic degradation of tetracycline under visible light
This study investigated the photocatalytic behaviors for the nanocomposite of TiO2 P25 and Semnan natural zeolite in the decomposition of tetracycline under visible light in an aqueous solution. The structural features of the composite were investigated by a series of complementary techniques that included X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), scanning elec...
متن کاملOrganosilane with gemini-type structure as the mesoporogen for synthesis of hierarchical porous ZSM-5 zeolite
A new kind of organosilane (1,6-bis (diethyl(3-trimethoxysilylpropyl)ammonium) hexane bromide) with a geminitype structure was prepared and used as a mesoporogen for the synthesis of hierarchical porous ZSM-5 zeolite. There are two quaternary ammonium centers along with double hydrolysable -RSi(OMe)3 fragments in the organosilane, which results in a strong interaction between this mesoporogen a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 22 شماره
صفحات -
تاریخ انتشار 2009